ASSESMENT OF HEAVY METAL CONCENTRATIONS IN WATER AND SEDIMENT OF MGBUODOHIA RIVER, OBIO\AKPOR LGA, RIVER STATE, NIGERIA
Abstract
This study quantified concentrations of selected heavy metals lead (Pb), manganese (Mn), zinc (Zn), cadmium (Cd), and chromium (Cr) in water and sediment from the Mgbuodohia River, Obio/Akpor Local Government Area, Rivers State, Nigeria. Water and sediment samples were collected at five sampling locations; in situ physicochemical parameters were recorded and metal concentrations were determined by atomic absorption spectrophotometry. Contamination status was evaluated using Contamination Factor (CF), Geoaccumulation Index (Igeo), and Pollution Load Index (PLI), and results were compared with World Health Organization and national guideline values. Descriptive statistics characterized spatial patterns, and Pearson and Spearman correlation analyses examined relationships among metals and between matrices. Results indicated spatial heterogeneity, with midstream sites exhibiting relatively higher concentrations for some metals. Most measured concentrations in both water and sediment were within guideline limits; CF and Igeo classifications identified low to moderate contamination at isolated sites, and PLI values were generally below unity. Significant correlations among selected metal pairs and between sediment and water for certain metals suggested common anthropogenic sources and active sediment–water exchange processes. The findings provide a baseline dataset for the Mgbuodohia River and support recommendations for routine monitoring, targeted source control, and community awareness to protect ecosystem and public health.
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References
Ali, H., Khan, E., & Ilahi, I. (2019). Environmental chemistry and ecotoxicology of hazardous heavy metals: Environmental persistence, toxicity, and bioaccumulation. Journal of Chemistry, 2019, Article 6730305.
American Public Health Association (APHA). (2017). Standard methods for the examination of water and wastewater (23rd ed.). American Public Health Association. ISBN: 978-0-87553-287-5
Chapman, D. (Ed.). (1996). Water quality assessments: A guide to the use of biota, sediments and water in environmental monitoring (2nd ed.). E & FN Spon.
Federal Ministry of Environment (FME). (2018). National environmental standards and regulations enforcement agency (Establishment) Act 2007 (as amended). Federal Republic of Nigeria.
Förstner, U., & Wittmann, G. T. W. (1981). Metal pollution in the aquatic environment (2nd ed.). Springer-Verlag. https://doi.org/10.1007/978-3-642-96511-1 (Original work published 2012 as e-book reprint)
Hakanson, L. (1980). An ecological risk index for aquatic pollution control: A sedimentological approach. Water Research, 14(8), 975–1001. https://doi.org/10.1016/0043-1354(80)90143-8
Jaishankar, M., Tseten, T., Anbalagan, N., Mathew, B. B., & Beeregowda, K. N. (2014). Toxicity, mechanism and health effects of some heavy metals. Interdisciplinary Toxicology, 7(2), 60–72. https://doi.org/10.2478/intox-2014-0009
Müller, G. (1969). Index of geoaccumulation in sediments of the Rhine River. GeoJournal, 2(3), 108–118.
Nwineewii, J. D., & Marcus, A. C. (2021). Concentration, ecological risk and enrichment factor assessment of selected heavy metals in sediments from New Calabar River, Nigeria. Journal of Applied Sciences and Environmental Management, 25(3), 415–422. [No DOI found]
Ololade, I. A., Lajide, L., & Oladoja, N. A. (2017). Assessment of heavy metals in water and sediment of New Calabar River, Niger Delta, Nigeria. Journal of Environmental Chemistry and Ecotoxicology, 9(3), 21–30.
Tchounwou, P. B., Yedjou, C. G., Patlolla, A. K., & Sutton, D. J. (2012). Heavy metal toxicity and the environment. Experientia Supplementum, 101, 133–164.
Tokalıoğlu, Ş., Kartal, Ş., & Elçi, L. (2000). Determination of heavy metals and their speciation in lake sediments by flame atomic absorption spectrometry after a four-stage sequential extraction procedure. Analytica Chimica Acta, 413(1–2), 33–40. https://doi.org/10.1016/S0003-2670(00)00763-0
Tomlinson, D. L., Wilson, J. G., Harris, C. R., & Jeffrey, D. W. (1980). Problems in the assessment of heavy-metal levels in estuaries and the formation of a pollution index. Helgoländer Meeresuntersuchungen, 33(1), 566–575.
UNESCO. (2020). The United Nations World Water Development Report 2020: Water and climate change. UNESCO. ISBN: 978-92-3-100371-4
World Health Organization (WHO). (2017). Guidelines for drinking-water quality (4th ed. incorporating the 1st addendum). World Health Organization. ISBN: 978-92-4-154995-0
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